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ProChimia/HS-(CH2)m-EGn-N3/TH 008-m11.n5-0.5/500 mg
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产品说明
Description
This unique line of thiols offers a range of truly exciting surface immobilization schemes. The EG linker makes these compounds suitable for inclusion in mixed SAMs resisting nonspecific absorption (with simple EGn thiols as the background; cf. cat # TH000 - TH005), and the azide group provides a biospecific handle for Sharpless "click" chemistry. (Angew. Chem. Int. Ed. 41, 2596, 2002) towards acetylene-bearing reagents.
It has been recently been shown that the click chemistry can be used to immobilize various (bio)molecules chemoselectively and in excellent yields
(J. Am. Chem. Soc. 127, 8600, 2005), and that it can be coupled with electrochemistry to allow for site-selective immobilization (J. Am. Chem. Soc. 128, 1794-1795, 2006 and also Science, Editor's Choice, 10 February, 2006). In the latter case, application of voltage bias to a gold microelectrode supporting azide-terminated SAM changed the redox state of an auxiliary copper catalyst, and thus activated the SAM for the "click" chemistry. By activating different microelectrodes at different times, it was possible to immobilize various molecules onto them. The capability of such sequential immobilization should prove extremely useful in the development of electrochemical microsensor arrays.
Note: Please see our related product Cat. FT 010-m11 (under Functionalized Thiols) and also silane analogs for functionalization of glass, Si and PDMS (under Silanes).
ProChimia
波兰 ProChimia 成立于 2001 年。专注于化学领域，纳米技术和生物技术领域，ProChimia 为化学和生化各种类型的表面和材料的改性提供了一流的解决方案。产品 用于官能化自组装单分子膜的化学物质，以及单分散金属（金、银、铜、铂、钯）和氧化铁 纳米粒子功能化与各种配体。产品被全球 2000 多组织使用，客户包括著名学术机构(哈佛大 学、麻省理工学院、斯坦福、伯克利、牛津、ETH等)以及领先的高科技公司（Intel、Fuji、IBM、Qiagene，等等）。
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