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Gelest/ALLYLTRIMETHYLSILANE/SIA0555.0/

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BoilingPoint:85-6°EINECSNumber:212-104-5MolecularWeight:114.26SpecificGravity:0.7193Flashpoint:7°C(45°F)HMISKey:2-4-0-XFormula:C6H14SiRefractiveIndex:1.4074TSCA:TSCAApplication:Keyreviews.1,2,3,4Carriesoutdeoxygenativeallylationofbenzylicalcohols.10Allylateslithiumalkoxidesw/lossofthelithiumoxide.11Formsbenzylichomoallylicalcoholsina3-componentreactionw/aldehydes.12Diallylatesketonesviatheirketals.13Undergoespolymerizationwithzirconocenecomplexes.5Providesfunctionalterminationoflivingcarbocationicpolymerizedpolyisobutylenes.6Allylatesdioxolanes.7Allylatesiminesunderfluoridecatalysis.8Providesalternativefortheformationoftrans-allyl-2,3-O-isopropylidene-protectedpyrrolidines.9Reference:1. HandbookforReagentsforOrganicSynthesis,ReagentsforSilicon-MediatedOrganicSynthesis,Fuchs,P.L.Ed.,JohnWileyandSons,Ltd.,2011,p.14-24.10.De,S.K.;Gibbs,R.A.TetrahedronLett.2005,46,8345.11. Kabalka,G.W.etal.Organometallics2007,26,4112.12. Kataki,D.;Phukan,P.TetrahedronLett.2009,50,1958.13.Galy,N.etal.Tetrahedron2011,67,1448.2.Weber,W.InSiliconReagentsforOrganicSynthesis;Springer-Verlag:1983,p173.3.Fleming,I.Synthesis1979,761.4.Hosomani,N.Acc.Chem.Res.1988,21,200.5.Habane,S.etal.Macromol.Chem.Phys.1998,199,2211.6.Wilczek,L.etal.J.Polym.Sci.,PartA:Polym.Chem.1987,25,3255.7.Dussault,P.H.;Liu,X.Org.Lett.1999,1,1391.8.Weng,D.K.etal.J.Org.Chem.1999,64,4233.9.DeArmas,P.etal.Org.Lett.2000,3,3513.Fieser:AdditionalProperties:Versatilesynthon-transfersallylgroup,highlynucleophilicdoublebond

Gelest

盖尔斯公司在世界范围内被公认为材料科学和技术的领导者和创新者.Gelest通过客户驱动的方式制造和提供硅烷、硅酮和金属有机化合物，为先进的技术市场服务。

Gelest Inc. is recognized world-wide as a leader and innovator in materials science and technology. Gelest manufactures and provides silane, silicone and metal-organic compounds serving advanced technology markets through a customer driven approach.